Comparative Analysis of the Electrical Properties of Nanocrystalline NiMoO4 Hydrate and α-NiMoO4 Obtained by Hydrothermal Method
| Authors | O.M. Popovych, I.M. Budzulyak , O.V. Popovych, V.O. Kotsyubynsky , L.S. Yablon |
| Affiliations |
Vasyl Stefanyk Precarpathian National University, 57, Shevchenko St., 76018 Ivano-Frankivsk, Ukraine |
| Е-mail | khemiiolha@gmail.com |
| Issue | Volume 13, Year 2021, Number 6 |
| Dates | Received 23 September 2021; revised manuscript received 02 December 2021; published online 20 December 2021 |
| Citation | O.M. Popovych, I.M. Budzulyak, O.V. Popovych, et al., J. Nano- Electron. Phys. 13 No 6, 06007 (2021) |
| DOI | https://doi.org/10.21272/jnep.13(6).06007 |
| PACS Number(s) | 81.07.Bc, 84.37.q |
| Keywords | Nickel molybdate, Hydrothermal synthesis (3) , Impedance analysis, Electrical conductivity (10) . |
| Annotation |
We have investigated the impedance behavior and electrical conductivity of nanocrystalline hydrate and α-phase of nickel molybdates obtained by hydrothermal method. Frequency behavior of the real impedance part of obtained nickel molybdates points at space charge polarization under the impact of an applied electric field. The imaginary impedance component of α-NiMoO4 substance proves the absence of relaxation in it, meaning that the transport of charge carriers between grains is possible in the whole frequency range. At the same time, we observe a temperature-dependent relaxation process for NiMoO4 hydrate in the temperature range 175-200 C caused by defects, namely vacancies. It has been shown that the conductivity of NiMoO4 hydrate at a direct current is equal to 4·10 – 5 S/m, whereas for NiMoO4 α-phase it is 1.5·10 – 4 S/m at room temperature due to the conditions for obtaining materials. The temperature dependencies of the frequency exponent s that we obtained make it possible to assert that the ac conductivity of NiMoO4 hydrate can be explained on the basis of the correlated barrier hopping model, whereas of α-NiMoO4 – by small polaron tunneling model. |
|
List of References |
Other articles from this number
1) Deep Impact of the n-c-Si Defect Density on Heterojunction with Intrinsic Thin Layer Solar Cells [06001-1-06001-4]2) Comparative Study of the Influence of c-Si:H, a-Si:H, pm-Si:H and c-SiOx as a Passivation Layer on the Performance of HIT n-c-Si Solar Cells [06002-1-06002-4]
3) Enhanced Humidity Sensing Properties of Surfactant-Free Hydrothermally Synthesized Tin Oxide Nanoparticles [06003-1-06003-5]
4) Modeling and Simulation of MOSFET (High-k Dielectric) Using Genetic Algorithms [06004-1-06004-5]
5) Design and Analysis of a High-Performance Capsule-Shaped 2D-Photonic Crystal Biosensor: Application in Biomedicine [06005-1-06005-6]
6) Comparative Study of Thermal and Optical Properties of PANI Based Binary Nanocomposites [06006-1-06006-4]
7) Hydrogen Treatment of SPR Film Sensors: Experiments and Theoretical Modeling [06008-1-06008-5]
8) The Ag Influence on the Surface States of TiO2, Optical Activity and Its Cytotoxicity [06009-1-06009-5]
9) Distribution of Excess Charge Carriers in Bilateral Macroporous Silicon with Different Thicknesses of Porous Layers [06010-1-06010-5]
10) Si- and Ge-FinFET Inverter Circuits Optimization Based on Driver to Load Transistor Fin Ratio [06011-1-06011-4]
11) On the Time Resolved Optogalvanic Spectroscopy of Neon in a Hollow Cathode Discharge [06012-1-06012-6]
12) Effect of the Content of Molybdenum Disilicide on the Microstructure and Phase Transformations of ZrB2-MoSi2-10Al Coatings upon Annealing in Air [06013-1-06013-4]
13) Optical Properties of ZnO Thin Film: A Simulation Study for Optoelectronic Applications [06014-1-06014-4]
14) Features of Photoelectric Processes in CdS/CdTe Thin Film Heterosystems with Nanoscale Layers in Back Contacts [06015-1-06015-6]
15) A Comparative Study on the Optoelectronic Performance of Undoped, Mg-doped and F/Mg Co-doped ZnO Nanocrystalline Thin Films [06016-1-06016-6]
16) Comparative Study and Characterization of Reduced Graphene Oxide (RGO) and Porous Reduced Graphene Oxide (P-RGO) Based on Coconut Shell Waste [06017-1-06017-6]
17) Effect of Reinforcing Particle Shape on the Behavior of Composites Materials [06018-1-06018-4]
18) Superparamagnetism in Si1 – xGex (B, Hf) Whiskers [06019-1-06019-5]
19) Topological Analysis of the Effect of Annealing on the Grain-Boundary Structure of Polysilicon Films [06020-1-06020-4]
20) Electrochemical Properties of Hybrid Supercapacitors Formed Based on Nanoporous Carbon and Nickel Tungstate [06021-1-06021-5]
21) Experimental Data on Dynamic Changes of Radio Pulses When They are Emitted by Piezoceramic Electromechanical Transducers [06022-1-06022-5]
22) Iron-Doped Titania: Synthesis, Structural, Magnetic and Photocatalytic Properties [06023-1-06023-7]
23) Properties of Amorphous Silica Synthesized from Copper-Smelting Slags [06024-1-06024-6]
24) Strengthening Mechanisms in the Surface Layer of Duralumin Modified by a High Current Pulsed Relativistic Electron Beam [06025-1-06025-6]
25) Analysis of Mechanisms to Increase the Industrial Silicon Solar Cell Efficiency [06026-1-06026-8]
26) Numerical Analysis of the Nanoparticle Dynamics in a Viscous Liquid: Deterministic Approach [06027-1-06027-5]
27) Energy and Frequency Properties of Planar n+-n-n+ Diodes with Active Side Boundary [06028-1-06028-4]
28) Methods for Calculating the Transfer Functions of Broadband Plate Piezoelectric Transducers with Transition Layers [06029-1-06029-6]
29) Evaluation of Device Fabrication from FET to CFET: A Review [06030-1-06030-8]
30) Analysis of Crosstalk Noise Using Graphene Nanoribbon Interconnects by Changing Wire Spacing and Electron Mean Free Path [06031-1-06031-4]
31) Investigation of the Structural, Electrical and Corrosion Properties of NbN Films Deposited by Magnetron Sputtering (DC Power Supply) Technique at Different Power [06032-1-06032-6]
32) Optical Properties of CuSCN/Stilbazolium Dye Hybrid Thin Films [06033-1-06033-4]
33) Performance Analysis of Gate All Around (GAA) MOSFET at Cryogenic Temperature for the Sub-Nanometer Regime [06034-1-06034-4]
34) Study and Design of Printed Rectangular Microstrip Antenna Arrays at an Operating Frequency of 27.5 GHz for 5G Applications [06035-1-06035-5]
35) Influence of the Angle of Incident Light on the Performance of Textured Silicon Solar Cells [06036-1-06036-5]
