Authors | B. Rebai1 , T. Messas1 , K. Mansouri2,3 , , B. Mamen1, B. Litouche4 , M. Hadji5, A. Berkia2 |
Affiliations |
1University Abbes Laghrour, Civil Engineering Department, 40000 Khenchela, Algeria 2UniversityAbbes Laghrour, Mechanical Engineering Department, 40000 Khenchela, Algeria 3Laboratory of Engineering and Sciences of Advanced Materials (ISMA), 40000 Khenchela, Algeria 4University Center Abdelhafid Boussouf, Mechanic and ElectroMechanic Department, 43000 Mila, Algeria 5Faculty of Sciences & Technology, Climatic Engineering Department, Mentouri Brothers University, Algeria |
Е-mail | billel.rebai@univ-khenchela.dz |
Issue | Volume 17, Year 2025, Number 4 |
Dates | Received 18 March 2025; revised manuscript received 21 August 2025; published online 29 August 2025 |
Citation | B. Rebai, T. Messas, et al., J. Nano- Electron. Phys. 17 No 4, 04034 (2025) |
DOI | https://doi.org/10.21272/jnep.17(4).04034 |
PACS Number(s) | 77.84. – s, 77.84.Lf, 78.66.Sq |
Keywords | Concrete resilience, Harsh environments, Compressive strength, Water absorption, Chemical exposure, Concrete additives, Sulfate degradation. |
Annotation |
This research pioneers nano-engineered concrete formulations to address accelerated degradation in harsh environments (seawater, acidic solutions, household wastewater). Conventional concrete suffers severe compressive strength loss (25 % in seawater, 56 days) and 35 % increased water absorption due to sulfate/chloride-induced microcracking and portlandite dissolution. Our solution integrates polycarboxylate ether superplasticizers (1 % bwoc) for reduced capillary porosity, vinsol resin air-entrainers (0.02 % bwoc) creating discontinuous micro-bubble barriers, and gluconic acid retarders (0.5 % bwoc) enabling homogeneous C-S-H nucleation. Rigorous testing under ASTM/EN protocols revealed nano-modified specimens limit strength degradation to 15 % in seawater and absorption increase to 15 % outperforming ordinary concrete by 40 % in key durability metrics. Advanced characterization (SEM-EDS/XRD/mercury porosimetry) confirmed refined pore structures (< 50 nm dominant pore diameter vs. > 200 nm in controls) and inhibited ettringite formation. The study establishes admixtures as multi-functional nano-modifiers that obstruct ionic diffusion pathways through electron barrier effects and optimized hydration kinetics, providing a transformative approach for marine and chemical-exposure infrastructure. |
List of References |